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Benzyl 2-chloroacetate

  • Name Benzyl 2-chloroacetate
  • CAS 140-18-1
  • Purity 99%
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Product Details

Bulk supply high purity Benzyl 2-chloroacetate 140-18-1, Paid sample available

  • Molecular Formula: C9H9ClO2
  • Molecular Weight: 184.622
  • Appearance/Colour: Colorless liquid. 
  • Vapor Pressure: 0.0189mmHg at 25°C 
  • Melting Point: 90 
  • Refractive Index: n20/D 1.525(lit.)  
  • Boiling Point: 252.847 °C at 760 mmHg 
  • Flash Point: 117.916 °C 
  • PSA: 26.30000 
  • Density: 1.202 g/cm3 
  • LogP: 1.96860 

Benzyl 2-chloroacetate(Cas 140-18-1) Usage

Safety Profile

Moderately toxic byintraperitoneal route. When heated todecomposition it emits toxic fumes of Cl- .

General Description

Benzyl chloroacetate is an ester.

InChI:InChI=1/C9H9ClO2/c10-6-9(11)12-7-8-4-2-1-3-5-8/h1-5H,6-7H2

140-18-1 Relevant articles

Transesterification of α-substituted esters mediated by potassium carbonate

Jańczewski, Dominik,Synoradzki, Ludwik,W?ostowski, Marek

, p. 420 - 422 (2003)

α-Substituted esters were efficiently an...

(meth)acrylate compound

-

Paragraph 0041-0043, (2021/03/11)

The invention relates to a (meth)acrylat...

FeCl2-mediated Nucleophilic Chlorination of Iodoalkanes Accelerated by Phenanthroline Ligand

Hwang, Joon Young,Shin, Jung Ha,Seong, Eun Young,Kang, Eun Joo

, p. 695 - 698 (2018/04/17)

-

Synthesis of some acyclic quaternary ammonium compounds. Alkylation of secondary and tertiary amines in a two-phase system

Kharlamov,Artyushin,Bondarenko

, p. 2445 - 2454 (2015/08/03)

A series of acyclic symmetrical and asym...

Dihaloiodoarenes: α,α-dihalogenation of phenylacetate derivatives

Tao, Jason,Tran, Richard,Murphy, Graham K.

supporting information, p. 16312 - 16315 (2013/12/04)

A hypervalent iodine reagent-based α-car...

140-18-1 Process route

chloroacetyl chloride
79-04-9

chloroacetyl chloride

benzyl alcohol
100-51-6,185532-71-2

benzyl alcohol

Benzyl chloroacetate
140-18-1

Benzyl chloroacetate

Conditions
Conditions Yield
With pyridine; In dichloromethane; at 25 ℃; for 0.25h;
86%
With silica gel HF-254/magnesium oxide; at 20 ℃; for 2.5h; chemoselective reaction; Green chemistry;
78%
With sulfuric acid; In chloroform; at 10 - 25 ℃; for 2h;
70%
benzyl iodoacetate
81867-37-0

benzyl iodoacetate

Benzyl chloroacetate
140-18-1

Benzyl chloroacetate

Conditions
Conditions Yield
With 1,10-Phenanthroline; iron(II) chloride; In acetonitrile; at 60 ℃; for 0.5h;
85%

140-18-1 Upstream products

  • 79-11-8
    79-11-8

    chloroacetic acid

  • 100-51-6
    100-51-6

    benzyl alcohol

  • 79-04-9
    79-04-9

    chloroacetyl chloride

  • 37003-25-1
    37003-25-1

    monochloroacetaldehyde dibenzyl acetal

140-18-1 Downstream products

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    53342-23-7

    benzyl morpholino-acetate

  • 102004-64-8
    102004-64-8

    benzyl 2-(azepan-1-yl)acetate

  • 6322-72-1
    6322-72-1

    (2-benzhydryloxy-ethyl)-benzyloxycarbonylmethyl-dimethyl-ammonium; chloride

  • 103-41-3
    103-41-3

    (E)-cinnamic acid benzyl ester

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