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Benzyl 2-chloroacetate
- Name Benzyl 2-chloroacetate
- CAS 140-18-1
- Purity 99%
Product Details
Bulk supply high purity Benzyl 2-chloroacetate 140-18-1, Paid sample available
- Molecular Formula: C9H9ClO2
- Molecular Weight: 184.622
- Appearance/Colour: Colorless liquid.
- Vapor Pressure: 0.0189mmHg at 25°C
- Melting Point: 90
- Refractive Index: n20/D 1.525(lit.)
- Boiling Point: 252.847 °C at 760 mmHg
- Flash Point: 117.916 °C
- PSA: 26.30000
- Density: 1.202 g/cm3
- LogP: 1.96860
Benzyl 2-chloroacetate(Cas 140-18-1) Usage
|
Safety Profile |
Moderately toxic byintraperitoneal route. When heated todecomposition it emits toxic fumes of Cl- . |
|
General Description |
Benzyl chloroacetate is an ester. |
InChI:InChI=1/C9H9ClO2/c10-6-9(11)12-7-8-4-2-1-3-5-8/h1-5H,6-7H2
140-18-1 Relevant articles
Transesterification of α-substituted esters mediated by potassium carbonate
Jańczewski, Dominik,Synoradzki, Ludwik,W?ostowski, Marek
, p. 420 - 422 (2003)
α-Substituted esters were efficiently an...
(meth)acrylate compound
-
Paragraph 0041-0043, (2021/03/11)
The invention relates to a (meth)acrylat...
FeCl2-mediated Nucleophilic Chlorination of Iodoalkanes Accelerated by Phenanthroline Ligand
Hwang, Joon Young,Shin, Jung Ha,Seong, Eun Young,Kang, Eun Joo
, p. 695 - 698 (2018/04/17)
-
Synthesis of some acyclic quaternary ammonium compounds. Alkylation of secondary and tertiary amines in a two-phase system
Kharlamov,Artyushin,Bondarenko
, p. 2445 - 2454 (2015/08/03)
A series of acyclic symmetrical and asym...
Dihaloiodoarenes: α,α-dihalogenation of phenylacetate derivatives
Tao, Jason,Tran, Richard,Murphy, Graham K.
supporting information, p. 16312 - 16315 (2013/12/04)
A hypervalent iodine reagent-based α-car...
140-18-1 Process route
-
-
79-04-9
chloroacetyl chloride
-
-
100-51-6,185532-71-2
benzyl alcohol
-
-
140-18-1
Benzyl chloroacetate
| Conditions | Yield |
|---|---|
|
With
pyridine;
In
dichloromethane;
at 25 ℃;
for 0.25h;
|
86%
|
|
With
silica gel HF-254/magnesium oxide;
at 20 ℃;
for 2.5h;
chemoselective reaction;
Green chemistry;
|
78%
|
|
With
sulfuric acid;
In
chloroform;
at 10 - 25 ℃;
for 2h;
|
70%
|
|
|
-
-
81867-37-0
benzyl iodoacetate
-
-
140-18-1
Benzyl chloroacetate
| Conditions | Yield |
|---|---|
|
With
1,10-Phenanthroline; iron(II) chloride;
In
acetonitrile;
at 60 ℃;
for 0.5h;
|
85%
|
140-18-1 Upstream products
-
79-11-8
chloroacetic acid
-
100-51-6
benzyl alcohol
-
79-04-9
chloroacetyl chloride
-
37003-25-1
monochloroacetaldehyde dibenzyl acetal
140-18-1 Downstream products
-
53342-23-7
benzyl morpholino-acetate
-
102004-64-8
benzyl 2-(azepan-1-yl)acetate
-
6322-72-1
(2-benzhydryloxy-ethyl)-benzyloxycarbonylmethyl-dimethyl-ammonium; chloride
-
103-41-3
(E)-cinnamic acid benzyl ester
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